After the attribute multipleValues="true" is added, and file saved back to its original location, you need to execute the command
rundll32 "C:\Program Files (x86)\PDF-ShellTools\PDFShellTools.dll",InstallPropertySchema from an
elevated command prompt. Have you done this?
Don't forget to change the path "C:\Program Files (x86)\", if you have PDF-ShellTools installed at a different folder.
The UninstallPropertySchema command, I previously stated as needed, is not necessary.
And there is no need to change to "Multi-value text" under the Edit/Draw settings, because if the type is set to "multipleValues", the default draw/editor will assume the Multi-value text anyway.
I've tried it here and this workaround works fine. There is no need to restart windows.
If you use the manager again, to change anything related to the custom fields, you will have to repeat the process, because the manager removes that "multipleValues" attribute from the schema file. Next release have this fixed (check attached screenshot).
The changes you show in your attachment seem to be OK. Even so, you may check the windows event viewer for any error that may be happening in the registration of the property schema.